1-Hydro-1,10-phenanthrolinium perchlorate and 1,10-Dihydro-1,10-phenanthrolinium Perchlorate in the Reaction of Electrocatalytic Production of Molecular Hydrogen

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Using the cyclic voltammetry method, the electrochemical and electrocatalytic properties for hydrogen evolution reaction of the 1-hydro-1,10-phenanthrolinium perchlorate (I) and 1,10-dihydro-1,10-phenanthrolinium perchlorate (II) in the presence of CF3COOH were studied. The presence of hydrogen atoms at nitrogen in heterocyclic compounds has a significant effect on the electrochemical properties and the efficiency of the electrocatalytic process. The transition from 1-hydro-1,10-phenanthrolinium perchlorate (I) to 1,10-dihydro-1,10-phenanthrolinium perchlorate (II) leads to an increase in the efficiency of the process (higher TOF and TON values), despite identical mechanisms. The DFT method was used to study the mechanisms of the processes taking place and identify key intermediates.

Sobre autores

A. Yudina

National Research Ogarev Mordovia State University

Autor responsável pela correspondência
Email: dolganov_sasha@mail.ru
ORCID ID: 0000-0002-1269-1609
Rússia, Bolshevistskaya st. 68, Saransk 430005

T. Boykova

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
Bolshevistskaya st. 68, Saransk 430005

O. Ganz

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
Rússia, Bolshevistskaya st. 68, Saransk 430005

L. Klimaeva

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
ORCID ID: 0000-0003-3050-4720
Rússia, Bolshevistskaya st. 68, Saransk 430005

Yu. Ulyakina

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
Rússia, Bolshevistskaya st. 68, Saransk 430005

A. Burmistrova

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
Rússia, Bolshevistskaya st. 68, Saransk 430005

T. Karpunina

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
Rússia, Bolshevistskaya st. 68, Saransk 430005

E. Okina

National Research Ogarev Mordovia State University

Email: dolganov_sasha@mail.ru
Rússia, Bolshevistskaya st. 68, Saransk 430005

Bibliografia

  1. Kibsgaard J., Chorkendorff I., Nat. Energy, 2019, 4, 430–433. doi: 10.1038/s41560-019-0407-1.
  2. Owusu P.A., Asumadu-Sarkodie S., Cogent Eng., 2016, 3, 1167990. doi: 10.1080/23311916.2016.1167990.
  3. Ball M., Wietschel M., Int. J. Electrochem. Sci., 2009, 34, 615–627. doi: 10.1016/j.ijhydene.2008.11.014.
  4. Chisholm G., Zhao T., Cronin L., Storing Energy, Elsevier, 2022, 559–591. doi: 10.1016/B978-0-12-824510-1.00015-5.
  5. Chen Z., Wei W., Song L., Ni B.-J., Sustainable Horizons, 2022, 1, 100002. doi: 10.1016/j.horiz.2021.100002.
  6. McHugh P.J., Stergiou A.D., Symes M.D., Adv. Energy Mater, 2020, 10, 2002453. doi: 10.1002/aenm.202002453.
  7. Eckenhoff W.T., McNamara W.R., Du P., Eisenberg R., BBA — Bioenergetics, 2013, 1827, 958–73. doi: 10.1016/j.bbabio.2013.05.003.
  8. Alrashedi A.A., Abdulaziz F., Khalaf M., Int. J. Electrochem. Sci., 2022, 17, 221227. doi: 10.20964/2022.12.37.
  9. Das M., Khan Z.B., Biswas A., Dey R.S., Inorg. Chem., 2022, 61, 18253–18259. doi: 10.1021/acs.inorgchem.2c03074.
  10. Wu Y., Rodríguez-López N., Villagrán D., Chem. Sci., 2018, 9, 4689–4695. doi: 10.1039/C8SC00093J.
  11. Dolganov, A.V., Tanaseichuk, B.S., Pryanichnikova, M.K., Ivleva, A.Y., Chernyaeva, O.Y., Grigoryan, K.A., Chugunova, E.A., Yurova, V.Y., J. Phys. Org. Chem., 2019, 32. doi: 10.1002/poc.3930.
  12. Dolganov, A.V., Tanaseichuk, B.S., Yurova, V.Y., Chernyaeva, O.Y., Okina, E.V., Balandina, A.V., Portnova, E.A., Kozlov, A.S., Solovyova, E.O., Yudina, A.D., Akhmatova, A.A., Lyukshina, Y.I., Int. J. Electrochem. Sci., 2019, 44, 21495–21505. doi: 10.1016/j.ijhydene.2019.06.067.
  13. Dolganov, A.V., Chernyaeva, O.Y., Kostryukov, S.G., Balandina, A.V., Solovyova, E.O., Yudina, A.D., Akhmatova, A.A., Lyukshina, Y.I., Int. J. Electrochem. Sci., 2020, 45, 501–507. doi: 10.1016/j.ijhydene.2019.10.175.
  14. Dolganov, A.V., Tanaseichuk, B.S., Tarasova, O.V., Chernyaeva, O.Yu., Selivanova, Yu.M., Yudina, A.D., Grigor′yan, K.A., Balandina, A.V., Yurova, V.Yu., Russ. J. Electrochem., 2019, 55, 807–812. doi: 10.1134/S1023193519080056.
  15. Felton G.A.N., Glass R.S., Lichtenberger D.L., Evans D.H., Inorg. Chem., 2006, 45, 9181–9184. doi: 10.1021/ic060984e.
  16. Roberts J.A.S., Bullock R.M., Inorg. Chem., 2013, 52, 3823–3835. doi: 10.1021/ic302461q.
  17. Helm M.L., Stewart M.P., Bullock R.M., DuBois M.R., DuBois D.L., Science, 2011, 333, 863–866. doi: 10.1126/science.1205864.
  18. Stephens P.J., Devlin F.J., Chabalowski C.F., Frisch M.J., J. Phys. Chem., 1994, 98, 11623–11627. doi: 10.1021/j100096a001.
  19. Ditchfield R., Hehre W.J., Pople J.A., J. Phys. Chem., 1971, 54, 724–728. doi: 10.1063/1.1674902.
  20. Schmidt M.W., Baldridge K.K., Boatz J.A., Elbert S.T., Gordon M.S., Jensen J.H., Koseki S., Matsunaga N., Nguyen K.A., Su S., Windus T.L., Dupuis M., Montgomery J.A., J. Comput. Chem., 1993, 14, 1347–1363. doi: 10.1002/jcc.540141112.

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar

Declaração de direitos autorais © Russian Academy of Sciences, 2025