ESTIMATION OF EFFICIENCY OF OXALIC ACID APPLICATION IN SOLUTION COMBUSTION SYNTHESIS OF CATALYST FOR PRODUCTION OF HYDROGEN AND CARBON FROM METHANE

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

In this work, the parameters of catalyst synthesis by solution combustion method using oxalic acid as a reducing agent, were investigated. The catalysts activity in the process of obtaining hydrogen and carbon nanofibers by the catalytic decomposition of methane has been determined. The effectiveness of using this reagent for the preparation of a nickel catalyst (90% Ni/10% Al2O3) that does not require preliminary reduction with hydrogen was shown. Based on the regression analysis, it was found that among the catalyst synthesis parameters, the yields of carbon and hydrogen are most strongly influenced by temperature.

Sobre autores

P. Kurmashov

Novosibirsk State Technical University

Autor responsável pela correspondência
Email: kurmaschov@gmail.com
Russian, 630073, Novosibirsk

M. Popov

Novosibirsk State Technical University; N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: kurmaschov@gmail.com
Russian, 630073, Novosibirsk; Russian, 119991, Moscow

A. Brester

Novosibirsk State Technical University

Email: kurmaschov@gmail.com
Russian, 630073, Novosibirsk

A. Ukhina

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences

Email: kurmaschov@gmail.com
Russian, 630090, Novosibirsk

A. Bannov

Novosibirsk State Technical University

Email: kurmaschov@gmail.com
Russian, 630073, Novosibirsk

Bibliografia

  1. Kuvshinov D.G., Kurmashov P.B., Bannov A.G., Popov M.V., Kuvshinov G.G. // Int. J. Hydrogen Energy. 2019. V. 44. № 31. P. 16271–16286. https://doi.org/10.1016/j.ijhydene.2019.04.179
  2. Shen Y., Lua A. // J. Power Sources. 2015. V. 280. P. 467–475. https://doi.org/10.1016/j.jpowsour.2015.01.057
  3. Wang H.Y., Lua A.C. // Chem. Eng. J. 2015. V. 262. P. 1077–1089. https://doi.org/10.1016/J.CEJ.2014.10.063
  4. Kenzhin R.M., Bauman Y.I., Volodin A.M., Mishakov I.V., Vedyagin A.A. // Appl. Surf. Sci. 2018. V. 427. P. 505–510. https://doi.org/10.1016/j.apsusc.2017.08.227
  5. Muto T., Asahara M., Miyasaka T., Asato K., Uehara T., Koshi M. // Chem. Eng. Sci. 2023. V. 274. P. 117931. https://doi.org/10.1016/j.ces.2022.117931
  6. Kurmashov P.B., Bannov A.G., Popov M.V., Kazakova A.A., Ukhina A.V., Kuvshinov G.G. // Russ. J. Appl. Chem. 2018. V. 91. № 11. P. 1874–1881. https://doi.org/10.1134/S1070427218110198
  7. Kurmashov P.B., Bannov A.G., Popov M.V., Brester A.E., Ukhina A.V., Ishenko A.V., Maksimovskii E.A., Tolsto-brova L.I., Chulkov A.O., Kuvshinov G.G. // Int. J. Energy Res. 2022. V. 46. № 9. P. 11957–11971. https://doi.org/10.1002/er.7964
  8. Kingsley J.J., Patil K.C. // Mater. Lett. 1988. V. 6. № 11–12. P. 427–432. https://doi.org/10.1016/0167-577X(88)90045-6
  9. Prakash A.S., Khadar A.M.A., Patil K.C., Hegde M.S. // J. Mater. Synth. Process. 2002. V. 10. P. 135–141. https://doi.org/10.1023/A:1021986613158
  10. Popov M.V., Bannov A.G // AIP Conf. Proc. 2022. V. 2390. № 1. P. 020060. https://doi.org/10.1063/5.0070001
  11. Ermakova M.A., Ermakov D.Yu., Kuvshinov G.G., Plyasova L.M. // J. Catal. 1999. V. 187. № 1. P. 77–84. https://doi.org/10.1006/jcat.1999.2562
  12. Kuvshinov G.G., Mogilnykh Yu.I., Kuvshinov D.G., Zaikovskii V.I., Avdeeva L.B. // Carbon. 1998. V. 36. № 1–2. P. 87–97. https://doi.org/10.1016/S0008-6223(97)00131-0
  13. Kuvshinov G.G., Popov M.V., Tonkodubov S.E., Kuvshinov G.G. // Russ. J. Appl. Chem. 2016. V. 89. № 11. P. 1777–1785. https://doi.org/10.1134/S1070427216110070
  14. Krutskii Yu.L., Bannov A.G., Sokolov V.V., Dykova K.D., Shinkarev V.V., Ukhina A.V., Maksimovskii E.A., Pichugin A.Yu., Solov’ev E.A., Krutskaya T.M., Kuvshinov G.G. // Nanotechnol. Russia. 2013. V. 8. № 3–4. P. 3212–3217. https://doi.org/10.1134/S1995078013020109
  15. Pichugin A.Yu., Maksimovskii E.A., Krutskaya T.M., Netskina O.V., Bataev I.A. // Ceram. Int. 2017. V. 43. № 3. P. 3212–3217. https://doi.org/10.1016/j.ceramint.2016.11.146
  16. Brester A.E., Golovakhin V.V., Novgorodtseva O.N., Lapekin N.I., Shestakov A.A., Ukhina A.V., Prosanov I.Yu., Maksimovskii E.A., Popov M.V., Bannov A.G. // Dokl. Chem. 2021. V. 501. № 2. P. 264–269. https://doi.org/10.1134/S0012500821120016
  17. Bannov A.G. Prášek J., Jašek O., Shibaev A.A., Zajíčková L. Gas sensing properties of carbon nanomaterials. In: Proc. of the 2016 39th International Spring Seminar on Electronics Technology (ISSE), Pilsen, Czech Republic, 18–22 May 2016. V. 2016. P. 449–451. https://doi.org/10.1109/ISSE.2016.7563238
  18. Bannov A.G., Popov M.V., Brester A.E., Kurmashov P.B. // Micromachines. 2021. V. 12. № 2. P. 186. https://doi.org/10.3390/mi12020186
  19. Shinkarev V.V., Glushenkov A.M., Kuvshinov G.G., Kuvshinov D.G. // Appl. Catal., B. 2009. V. 85. № 3–4. P. 180–191. https://doi.org/10.1016/j.apcatb.2008.07.011
  20. Shinkarev V.V., Glushenkov A.M., Kuvshinov G.G., Kuvshinov D.G. // Carbon. 2010. V. 48. № 7. P. 2004–2012. https://doi.org/10.1016/j.carbon.2010.02.008
  21. Bannov A.G., Uvarov N.F., Shilovskaya S.M., Kuvshi-nov G.G. // Nanotechnol. Russia. 2012. V. 7. № 3–4. P. 169–177. https://doi.org/10.1134/S1995078012020048
  22. Dong Y., Ni Q., Li L., Fu Y. // Mater. Lett. 2014. V. 132. P. 206–209. https://doi.org/10.1016/j.matlet.2014.06.084
  23. Li Y., Li D., Wang G. // Catal. Today. 2011. V. 162. № 1. P. 1–48. https://doi.org/10.1016/j.cattod.2010.12.042
  24. Hadian M., Marrevee D.P.F., Buist K.A., Reesink B.H., Bos R., Bavel A.P., Kuipers H.A.M. // Chem. Eng. Sci. 2022. V. 260. № 22. P. 117938. https://doi.org/10.1016/j.ces.2022.117938
  25. Roslyakov S.I., Kovalev D.Yu., Rogachev A.S., Manu-kyan H., Mukas’yan A.S. // Dokl. Phys. Chem. 2013. V. 449. № 1. P. 48–51. https://doi.org/10.1134/S0012501613030068
  26. Kachala V.V., Khemchyan L.L., Kashin A.S., Orlov N.V., Grachev A.A., Zalesskiy S.S., Ananikov V.P. // Russ. Chem. Rev. 2013. V. 82. № 7. P. 648–685. https://doi.org/10.1070/rc2013v082n07abeh004413

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2.

Baixar (50KB)
Metadados
3.

Baixar (87KB)
Metadados
4.

Baixar (114KB)
Metadados
5.

Baixar (79KB)
Metadados
6.

Baixar (76KB)
Metadados
7.

Baixar (1MB)
Metadados
8.

Baixar (1MB)
Metadados

Declaração de direitos autorais © П.Б. Курмашов, М.В. Попов, А.Е. Брестер, А.В. Ухина, А.Г. Баннов, 2023