Active and stable Ni/Al2O3–(Zr+Ce)O2 catalyst for syngas production via glycerol dry reforming

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

A nickel-based catalyst supported on alumina-zirconia-ceria oxides was investigated to evaluate its performance in the dry reforming of glycerol with CO₂. The reaction was carried out at 700°C, atmospheric pressure and a glycerol/CO₂ molar ratio of 1. The catalyst showed stable operation for 7 h and achieved glycerol and CO₂ conversions of 60 and 47%, respectively, with H₂ and CO yields of 48 and 58%. Thermogravimetric analysis revealed the presence of carbon deposits, which, however, did not result in a significant loss of activity. These results highlight the potential of the synthesized catalyst for glycerol conversion for the production of syngas and hydrogen from renewable feedstock.

Толық мәтін

Рұқсат жабық

Авторлар туралы

Yu. Fionov

Patrice Lumumba Peoples’ Friendship University of Russia (RUDN University)

Хат алмасуға жауапты Автор.
Email: fionovyuri@gmail.com

Department of Physical and Colloid Chemistry

Ресей, Miklukho-Maklaya St., 6, Moscow, 117198

S. Semenova

Patrice Lumumba Peoples’ Friendship University of Russia (RUDN University)

Email: fionovyuri@gmail.com

Department of Physical and Colloid Chemistry

Ресей, Miklukho-Maklaya St., 6, Moscow, 117198

S. Khaibullin

Patrice Lumumba Peoples’ Friendship University of Russia (RUDN University)

Email: fionovyuri@gmail.com

Department of Physical and Colloid Chemistry

Ресей, Miklukho-Maklaya St., 6, Moscow, 117198

E. Fionova

MIREA – Russian Technological University

Email: fionovyuri@gmail.com

Department of Digital and Additive Technologies

Ресей, prosp. Vernadskogo, 78, bldg. 4, Moscow, 119454

I. Bratchikova

Patrice Lumumba Peoples’ Friendship University of Russia (RUDN University)

Email: fionovyuri@gmail.com

Department of Physical and Colloid Chemistry

Ресей, Miklukho-Maklaya St., 6, Moscow, 117198

A. Kharlanov

Lomonosov Moscow State University, Faculty of Chemistry

Email: fionovyuri@gmail.com
Ресей, GSP-1, Leninskiye Gory, 1, bldg. 3, Moscow, 119991

A. Zhukova

Patrice Lumumba Peoples’ Friendship University of Russia (RUDN University)

Email: pylinina@list.ru

Department of Physical and Colloid Chemistry

Ресей, Miklukho-Maklaya St., 6, Moscow, 117198

Әдебиет тізімі

  1. Kolesárová N., Hutňan M., Bodík I., Špalková V. // BioMed Res. Int. 2011. V. 2011. 126798. https://doi.org/10.1155/2011/126798
  2. Cheng C.K., Lim R.H., Ubil A., Chin S.Y., Gimbun J. // Adv. Mater. Phys. Chem. 2012. V. 2. 24B043. https://doi.org/10.4236/ampc.2012.24B043
  3. Schwengber C.A., Alves H.J., Schaffner R.A., Alves da Silva F., Sequinel R., Rossato Bach V., Ferracin R.J. // Renew. Sustain. Energy Rev. 2016. V. 58. P. 259. https://doi.org/10.1016/j.rser.2015.12.279
  4. Sadykov V.A., Simonov M.N., Belpalko Y.N., Bobrova L.N., Eremeev N.F., Arapova M.V., Smal’ E.A., Mezentseva N.V., Pavlova S.N. // Kinet. Catal. 2019. Vol. 60. № 5. Р. 582. https://doi.org/10.1134/S0023158419050082
  5. Sabri F., Idem R., Ibrahim H. // Ind. Eng. Chem. Res. 2018. V. 57. P. 2486. https://doi.org/10.1021/acs.iecr.7b04582
  6. Pairojpiriyakul T., Kiatkittipong W., Assabumrungrat S., Croiset E. // Int. J. Hydrogen Energy. 2014. V. 39. P. 159. https://doi.org/10.1016/j.ijhydene.2013.09.148
  7. Mohd Arif N.N., Zainal Abidin S., Osazuwa O.U., Vo D.-V.N., Azizan M.T. // Int. J. Hydrogen Energy. 2019. V. 44. P. 20857. https://doi.org/10.1016/j.ijhydene.2018.06.084
  8. Kamonsuangkasem K., Therdthianwong S., Therdthianwong A. // Fuel Process. Technol. 2013. V. 106. P. 695. https://doi.org/10.1016/j.fuproc.2012.10.003
  9. Iriondo A., Cambra J.F., Barrio V.L., Guemez M.B., Arias P.L., Sanchez-Sanchez M.C., Navarro R.M., Fierro J.L.G. // Appl. Catal. B: Environ. 2011. V. 106. P. 83. https://doi.org/10.1016/j.apcatb.2011.05.009
  10. Tamošiūnas A., Gimžauskaitė D., Aikas M., Uscila R., Zakarauskas K. // Int. J. Hydrogen Energy. 2022. V. 47. P. 12219. https://doi.org/10.1016/j.ijhydene.2021.06.203
  11. Sahraei O.A.Z., Larachi F., Abatzoglou N., Iliuta M.C. // Appl. Catal. B: Environ. 2017. V. 219. P. 183. https://doi.org/10.1016/j.apcatb.2017.07.039
  12. Lee H.C., Siew K.W., Khan M.R., Chin S.Y., Cheng C.K. // J. Energy Chem. 2014. V. 23. P. 645. https://doi.org/10.1016/S2095-4956(14)60196-0
  13. Siew K.W., Lee H.C., Gimbun J., Cheng C.K. // J. Energy Chem. 2014. V. 23. P. 15. https://doi.org/10.1016/S2095-4956(14)60112-1
  14. Siew K.W., Lee H.C., Gimbun J., Chin S.Y., Khan M.R., Taufiq-Yap Y.H., Cheng C.K. // Renew. Energy. 2015. V. 74. P. 441. https://doi.org/10.1016/j.renene.2014.08.048
  15. Wang X., Li M., Wang M., Wang H., Li S., Wang S., Ma X. // Fuel. 2009. V. 88. P. 2148. https://doi.org/10.1016/j.fuel.2009.01.015
  16. Yu J., Odriozola J.A., Reina T.R. // Catalysts. 2019. V. 9. P. 1015. https://doi.org/10.3390/catal9121015
  17. Bychkov V.Y., Tulenin Y.P., Gorensberg A.Y., Korchak V.N. // Kinet. Catal. 2021. V. 62. № 1. P. 181. https://doi.org/10.1134/S0023158421010018
  18. Bychkov V.Y., Tyulenin Y.P., Korchak V.N. // Kinet. Catal. 2003. V. 44. P. 353. https://doi.org/10.1023/A:1024494918755
  19. Roslan N.A., Zainal Abidin S., Osazuwa O.U., Chin S.Y., Taufiq-Yap Y.H. // Int. J. Hydrogen Energy. 2021. V. 46. P. 30959. https://doi.org/10.1016/j.ijhydene.2021.03.162
  20. Tavanarad M., Meshkani F., Rezaei M. // J. CO2 Util. 2018. V. 24. P. 298. https://doi.org/10.1016/j.jcou.2018.01.009
  21. Fionov Y., Khlusova K., Chuklina S., Mushtakov A., Fionov A., Zhukov D., Averin A., Zhukova A. // Fuel. 2024. V. 376. 132685. https://doi.org/10.1016/j.fuel.2024.132685
  22. Golestani Kashani M., Ramezani Y., Meshkani F. // Mater. Today Commun. 2024. V. 40. 109999. https://doi.org/10.1016/j.mtcomm.2024.109999
  23. Memarian Z., Meshkani F. // Fuel. 2025. In press. https://doi.org/10.1016/j.fuel.2025.134902
  24. Huang L., Li D., Tian D., Jiang L., Li Z., Wang H., Li K. // Energy Fuel. 2022. V. 36. № 10. P. 5102. https://doi.org/10.1021/acs.energyfuels.2c00523
  25. Zhukova A.I., Chuklina S.G., Maslenkova S.A. // Catal. Today. 2021. V. 379. P. 159. https://doi.org/10.1016/j.cattod.2021.02.015
  26. Zhukova A., Fionov Y., Semenova S., Khaibullin S., Chuklina S., Maslakov K., Zhukov D., Isaikina O., Mushtakov A., Fionov A. // J. Phys. Chem. C. 2024. V. 128. № 47. P. 20177. https://doi.org/10.1021/acs.jpcc.4c07213
  27. Salehi S., Alavi S.M., Rezaei M., Akbari E., Varbar M. // J. CO2 Util. 2024. V. 81. 102737. https://doi.org/10.1016/j.jcou.2024.102737
  28. Harun N., Gimbun J., Azizan M.T., Zainal Abidin S. // Bull. Chem. React. Eng. Catal. 2016. V. 11. № 2. P. 220. https://doi.org/10.9767/bcrec.11.2.553.220-229
  29. Golestani Kashani M., Ramezani Y., Meshkani F. // Mater. Res. Bull. 2025. V. 182. 113135. https://doi.org/10.1016/j.materresbull.2024.113135
  30. Roslan N.A., Zainal Abidin S., Osazuwa O.U., Chin S.Y., Taufiq-Yap Y.H. // Fuel. 2022. V. 314. 123050. https://doi.org/10.1016/j.fuel.2021.123050
  31. Lyu Y., Jocz J., Xu R., Stavitski E., Sievers C. // ACS Catal. 2020. V. 10. № 19. P. 11235. https://doi.org/10.1021/acscatal.0c02426
  32. Huang Y., Li X., Zhang Q., Vinokurov V.A., Huang W. // Fuel. 2022. V. 310. 122449. https://doi.org/10.1016/j.fuel.2021.122449
  33. Wang Z., Cao X.-M., Zhu J., Hu P. // J. Catal. 2014. V. 311. P. 469. https://doi.org/10.1016/j.jcat.2013.12.015
  34. Harun N., Gimbun J., Azizan M.T., Zainal Abidin S. // Bull. Chem. React. Eng. Catal. 2016. V. 11. P. 220. https://doi.org/10.9767/bcrec.11.2.553.220-229
  35. Donphai W., Faungnawakij K., Chareonpanich M., Limtrakul J. // Appl. Catal. A: Gen. 2014. V. 475. P. 16. https://doi.org/10.1016/j.apcata.2014.01.014
  36. Zhukova A., Fionov Y., Chuklina S., Mikhalenko I., Fionov A.V., Isaikina O., Zhukov D.Y., de Lima A.M. // Energy Fuel. 2024. V. 38. P. 482. https://doi.org/10.1021/acs.energyfuels.3c03421
  37. Zhang G., Wang Y., Li X., Bai Y., Zheng L., Wu L., Han X. // Ind. Eng. Chem. Res. 2018. V. 57. № 50. P. 17076. https://doi.org/10.1021/acs.iecr.8b03612
  38. Weiss B.P., Kim S.S., Kirschvink J.L., Kopp R.E., Sankaran M., Kobayashi A., Komeili A. // Earth Planet. Sci. Lett. 2004. V. 224. P. 73. https://doi.org/10.1016/j.epsl.2004.04.024
  39. Manukyan A.S., Mirzakhanyan A.A., Badalyan G.R., Shirinyan G.H., Fedorenko A.G., Lianguzov N.V., Yuzyuk Y.I., Bugaev L.A., Sharoyan E.G. // J. Nanopart. Res. 2012. V. 14. P. 982. https://doi.org/10.1007/s11051-012-0982-6
  40. Zhou L., Li L., Wei N., Li J., Basset J.-M. // ChemCatChem. 2015. V. 7. № 16. P. 2508. https://doi.org/10.1002/cctc.201500379
  41. Pegios N., Bliznuk V., Theofanidis S.A., Galvita V.V., Marin G.B., Palkovits R., Simeonov K. // Appl. Surf. Sci. 2018. V. 452. P. 239. https://doi.org/10.1016/j.apsusc.2018.04.229
  42. Bannov A.G., Popov M.V., Kurmashov P.B. // J. Therm. Anal. Calorim. 2020. V. 142. P. 349. https://doi.org/10.1007/s10973-020-09647-2

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2. Fig. 1. Scheme of the setup for studying the GCR process. The setup consists of gas sources (cylinders), a pressure and gas flow control block – regulators and gas flow controllers (marked as RFC in the scheme), a glycerol feed system – syringe pump, a reactor (the sample was placed between two layers of quartz wool in the center of the quartz tube), a furnace, a specialized condenser for separating liquid tarry products from gaseous ones, a chromatograph with a dosing valve for sampling, column separation of products and their sequential analysis by a thermal conductivity detector (TCD) and a flame ionization detector (FID).

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3. Fig. 2. Time dependences of CO2 and glycerol conversions (a) and yields of GCR reaction products (b) in the presence of the Ni/AZ catalyst. Dashed lines show the corresponding values in the absence of the catalyst.

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4. Fig. 3. Dependence of the H2/CO ratio on time during a 7 h stability test of the Ni/AZ catalyst in the GCR reaction. The dashed line shows the H2/CO ratio in the absence of the catalyst.

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5. Fig. 4. Dependence of the carbon mass in the gas phase at the reactor outlet on time. The dashed line shows the amount of carbon fed into the reactor.

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6. Fig. 5. EPR spectra of the Ni/AZ catalyst sample before and after the GCR process.

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7. Fig. 6. EPR signal width and asymmetry factor for the Ni/AZ catalyst sample before and after the GCR process.

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8. Fig. 7. TGA analysis of the catalyst after 7 h of glycerol dry reforming reaction: (a) – change in sample mass versus temperature; (b) – derivative of sample mass change versus temperature.

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