Mixed Ligand Zinc Complexation with Ornithine and Histidine in Aqueous Solution

M. G. Nikitina; Никитина М. Г.; M. S. Gruzdev; Груздев М. С.; D. F. Pyreu; Пырэу Д. Ф.

doi:10.31857/S0044457X22700167

Mixed Ligand Zinc Complexation with Ornithine and Histidine in Aqueous Solution

Авторлар: Nikitina M.G.¹, Gruzdev M.S.¹, Pyreu D.F.²
Мекемелер:
1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences
2. Ivanovo State University
Шығарылым: Том 68, № 3 (2023)
Беттер: 363-372
Бөлім: ФИЗИКОХИМИЯ РАСТВОРОВ
URL: https://ter-arkhiv.ru/0044-457X/article/view/665290
DOI: https://doi.org/10.31857/S0044457X22700167
EDN: https://elibrary.ru/JFWMYN
ID: 665290

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Ашық рұқсат
Рұқсат жабық

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Рұқсат жабық

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Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

The formation of mixed-ligand complexes of various compositions in the Zn–L-histidine (His)–L-ornithine (Orn) system has been studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log K, ΔrG0 ΔrH, ΔrS) of the reactions of their formation at 298.15 K and ionic strength I = 0.5 (KNO3) have been calculated. Based on the comparative analysis of thermodynamic parameters, the most probable method for the coordination of amino acid residues in mixed complexes has been proposed.

Негізгі сөздер

mixed ligand complexation, histidine, ornithine, calorimetry, zinc, denticity

Әдебиет тізімі

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