MICROSTRUCTURE OF A CrSi2 TRANSITION LAYER PRODUCED BY HOT PRESSING OF Cr AND Si

M. S. Lukasov; Лукасов М. С.; N. A. Arkharova; Архарова Н. А.; A. S. Orekhov; Орехов А. С.; E. V. Rakova; Ракова Е. В.; F. Yu. Solomkin; Соломкин Ф. Ю.; V. V. Klechkovskaya; Клечковская В. В.

doi:10.31857/S002347612360026X

MICROSTRUCTURE OF A CrSi2 TRANSITION LAYER PRODUCED BY HOT PRESSING OF Cr AND Si

Authors: Lukasov M.S.¹, Arkharova N.A.¹, Orekhov A.S.¹, Rakova E.V.¹, Solomkin F.Y.², Klechkovskaya V.V.¹
Affiliations:
1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, Moscow, 119333 Russia
2. Ioffe Institute, Russian Academy of Sciences, St. Petersburg, 194021 Russia
Issue: Vol 68, No 4 (2023)
Pages: 615-620
Section: НАНОМАТЕРИАЛЫ, КЕРАМИКА
URL: https://ter-arkhiv.ru/0023-4761/article/view/673421
DOI: https://doi.org/10.31857/S002347612360026X
EDN: https://elibrary.ru/IBYRNK
ID: 673421

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Abstract

Hot pressing of a Si single crystal in the bulk of electrolytic Cr powder at 1213 K, with subsequent annealing in air, leads to the formation of an intermediate polycrystalline silicide layer at the interface between the initial components. The phase composition and microstructure of the transition layer and its vicinity were investigated by scanning electron microscopy, X-ray energy-dispersive microanalysis, and electron backscatter diffraction. The transition layer has a crystal structure of the hexagonal phase of chromium disilicide (sp. gr. P6222). An additional annealing up to 120 h leads to insignificant recrystallization of small grains into larger ones.

Keywords

ULTRAFAST MAGNETIC DYNAMICS, Co/Pt MULTILAYER STRUCTURES

References

Burkov A.T., Ivanov Y.I. // Silicide Thermoelectrics. In Advanced Thermoelectric Materials / Ed. Park C.R. 2019. V. 165.
Gel’d P.V., Sidorenko F.A. // Silicides of Transition Metals of the Fourth Period. M.: Metallurgiya, 1971. P. 90.
Gokhale A.B., Abbaschian G.J. // J. Phase Equilibria. 1987. V. 8. P. 474. https://doi.org/10.1007/BF02893156
Okamoto H. // J. Phase Equilibria. 2001. V. 22 P. 593. https://doi.org/10.1361/105497101770332866
Boren B. // Archive Chem., Mineral. Geol. 1933. V. 11. P. 1.
Dauben C.H., Templeton D.H., Myers C.E. // J. Phys. Chem. 1956. V. 60. P. 443. https://doi.org/10.1021/j150538a015
Tanaka K., Nawata K., Koiwa M. et al. // Mat. Res. Soc. Symp. Proc. 2001. V. 646. P. 4.3.1.
Соломкин Ф.Ю., Суворова Е.И., Зайцев В.К. и др. // ЖТФ. 2011. Т. 81. № 2. С. 147.
Соломкин Ф.Ю., Зайцев В.К., Новиков С.В. и др. // ЖТФ. 2013. Т. 83. № 2. С. 141.
Соломкин Ф.Ю., Зайцев В.К., Картенко Н.Ф. и др. // ЖТФ. 2010. Т. 80. № 1. С. 152.
Соломкин Ф.Ю., Зайцев В.К., Картенко Н.Ф. и др. // ЖТФ. 2010. Т. 80. № 5. С. 157.
Fedorov M., Zaitsev V. // Thermoelectrics Handbook: Macro to Nano / Ed. Rowe D.M. N.Y.: CRC press, 2006. P. 31.
Burkov A., Vinzelberg H., Schumann J. et al. // J. Appl. Phys. 2004. V. 95. № 12. P. 7903.
Novikov S.V., Burkov A.T., Schumann J. // J. Electron. Mater. 2014. V. 43. № 6. P. 2420.
Novikov S.V., Burkov A.T., Schumann J. // J. Alloys Compd. 2013. V. 557. P. 239.
Hielscher R., Schaeben C. // J. Appl. Cryst. 2008. V. 41. P. 1024.