SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS OF HIGH-ENTROPY CARBIDES IN THE REGIME OF A GASLESS THERMAL EXPLOSION

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详细

High-entropy carbides are a new class of inorganic compounds promising for a wide range of applications. The paper presents a new concept for the synthesis of powders of high-entropy carbides by the method of self-propagating high-temperature synthesis (SHS) in the gasless thermal explosion mode from previously mechanically synthesized and structured reaction mixtures. For the first time, high-entropy carbides TaTiNbVWC5 and TaNbVMoWC5 were obtained by this method, their crystal structure was determined, which was compared with similar compositions obtained by sintering.

作者简介

Yu. Vergunova

Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka

S. Vadchenko

Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

编辑信件的主要联系方式.
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka

I. Kovalev

Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka

D. Kovalev

Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka

A. Rogachev

Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka

M. Alymov

Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka

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版权所有 © Ю.С. Вергунова, С.Г. Вадченко, И.Д. Ковалев, Д.Ю. Ковалев, А.С. Рогачев, М.И. Алымов, 2023