SYNTHESIS OF HYDROGENATED  MESO -TETRAPYRIDYLPORPHYRINS WITH A CONTROLLED COMPOSITION

A. V. Lyubimtsev; Любимцев А. В.; A. S. Semeikin; Семейкин А. С.; M. O. Koifman; Койфман М. О.; O. I. Koifman; Койфман О. И.

doi:10.31857/S2686953522600465

SYNTHESIS OF HYDROGENATED MESO-TETRAPYRIDYLPORPHYRINS WITH A CONTROLLED COMPOSITION

Authors: Lyubimtsev A.V.¹, Semeikin A.S.¹, Koifman M.O.¹, Koifman O.I.¹
Affiliations:
1. Ivanovo State University of Chemistry and Technology
Issue: Vol 508, No 1 (2023)
Pages: 39-49
Section: CHEMISTRY
URL: https://ter-arkhiv.ru/2686-9535/article/view/651991
DOI: https://doi.org/10.31857/S2686953522600465
EDN: https://elibrary.ru/EVXGPT
ID: 651991

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Abstract
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Abstract

The work is devoted to the development of a method for obtaining a highly sensitive composition of a controlled composition containing cationic water-soluble 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)chlorine and 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)bacteriochlorin. The process of diimide reduction of 5,10,15,20-tetrakis(pyridin-3-yl)porphine in pyridine and in the absence of a solvent has been studied. It is shown that the reduction in the alloy significantly reduces the reaction time (from 12 to 1.5 h) and allows to obtain compositions with a yield of up to 90%.

Keywords

porphyrin, chloride, bacteriochlorin, diimide reduction

References

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