Non-Isocyanate Poly(Siloxane-Urethanes) Based on Oligodimethylsiloxanes Containing Aminopropyl and Ethoxy Substituents

E. S. Trankina; Транкина Е. С.; A. Yu. Kazantseva; Казанцева А. Ю.; D. A. Khanin; Ханин Д. А.; S. E. Lyubimov; Любимов С. Е.; E. G. Kononova; Кононова Е. Г.; Yu. S. Andropova; Андропова У. С.; A. M. Muzafarov; Музафаров А. М.

doi:10.31857/S2308114723700437

Non-Isocyanate Poly(Siloxane-Urethanes) Based on Oligodimethylsiloxanes Containing Aminopropyl and Ethoxy Substituents

作者: Trankina E.S.¹, Kazantseva A.Y.¹, Khanin D.A.¹, Lyubimov S.E.¹, Kononova E.G.¹, Andropova Y.S.², Muzafarov A.M.¹^,2
隶属关系:
1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
期: 卷 65, 编号 2 (2023)
页面: 164-173
栏目: Articles
URL: https://ter-arkhiv.ru/2308-1147/article/view/674792
DOI: https://doi.org/10.31857/S2308114723700437
EDN: https://elibrary.ru/GCQLIT
ID: 674792

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Environmentally friendly method for the synthesis of crosslinked poly(siloxane-urethanes) avoiding the use of toxic isocyanates has been presented. The synthesis has been performed in two stages: at the first stage, non-isocyanate poly(siloxane-urethanes) have been synthesized via aminolysis of cyclocarbonates (differing in the structure and functionality) with oligomer dimethylsiloxanes bearing aminopropyl and ethoxy substituents, and crosslinked non-isocyanate poly(siloxane-urethanes) have been obtained via hydrolysis of the ethoxy groups with air moisture. According to the TGA data, processes of thermooxidative decomposition of the non-isocyanate poly(siloxane-urethanes) begin at 240‒260°C, depending on the structure of the organic block. Structural organization of the films has been investigated and glass transition temperature of two blocks (flexible siloxane and rigid urethane ones) has been determined by means of DSC and TMA. Surface of the film samples of non-isocyanate poly(siloxane-urethanes) has been assessed by means of scanning electron microscopy.

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