Application of pervaporation and vapor-phase membrane method for concentrating of furfural from aqueous solutions

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Рұқсат жабық Рұқсат берілді
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Аннотация

The relevance of increasing furfural production is supported by the expanding range of its applications. Furfural is produced exclusively through biomass hydrolysis, and rectification—which involves significant capital and operational costs—is currently the predominant method for obtaining commercial-grade furfural. Improving the efficiency of furfural concentration and reducing energy consumption can be achieved through membrane technology. This paper reviews the current state of research on the application of pervaporation and vapor-phase membrane separation, membrane materials, and membranes for furfural concentration. An analysis of published experimental data is presented, including an assessment of the membrane’s contribution to the separation process. It is shown that the furfural/water separation factor during phase transition is approximately 7 for a solution containing 6 wt.% furfural and exhibits weak temperature dependence. For a PDMS (polydimethylsiloxane) membrane, the furfural/water separation factor from 3.9 to 7.5. Using mathematical modeling of the vapor-phase membrane separation of furfural from hydrolysate, the expected process performance was calculated for an available PDMS-based membrane. The advantages of membrane technology over rectification are demonstrated: Production of a vapor stream with a higher organic phase content (35–50 wt.% vs. 27 wt.%). Higher proportion of furfural directed for further purification after decantation (87% of the initial stream vs. 70%).

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Авторлар туралы

A. Kozlova

Topchiev Institute of Petrochemical Synthesis RAS

Хат алмасуға жауапты Автор.
Email: a_a_kozlova@ips.ac.ru
Ресей, Leninsky Prospekt, 29, Moscow, 119991

V. Grudkovskaya

Topchiev Institute of Petrochemical Synthesis RAS

Email: a_a_kozlova@ips.ac.ru
Ресей, Leninsky Prospekt, 29, Moscow, 119991

M. Afokin

Topchiev Institute of Petrochemical Synthesis RAS

Email: a_a_kozlova@ips.ac.ru
Ресей, Leninsky Prospekt, 29, Moscow, 119991

M. Shalygin

Topchiev Institute of Petrochemical Synthesis RAS

Email: a_a_kozlova@ips.ac.ru
Ресей, Leninsky Prospekt, 29, Moscow, 119991

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2. Fig. 1. Furfural platform for the production of various types of biofuels [10].

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3. Fig. 2. Schematic representation of mass transfer in pervaporation.

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4. Fig. 3. Schematic representation of mass transfer in the vapor-phase membrane method.

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5. Fig. 4. Phase diagram of furfural/water systems at 60°C (1) and 90°C (2) and butanol/water at 60°C (3), where x is the content of components in the liquid phase, y is in the vapor phase.

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6. Fig. 5. The p-x-y diagram of the furfural/water system at 60°C (1) and 90°C (2), x is the furfural content in the liquid phase, y is in the vapor phase, p is the pressure of the vapor mixture above the solution.

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7. Fig. 6. Available literature data on the properties of membranes in separating a water/furfural mixture in Robson diagram coordinates.

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8. Fig. 7. Scheme of the process of vapor-phase membrane concentration of furfural: VN – vacuum pump, D – decanter, K – condenser, MM – membrane module. The furfural content is given without taking into account the carrier gas, the compositions of the permeate and retentate are indicated for a furfural extraction degree of 50%.

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9. Fig. 8. Dependence of furfural content in permeate (solid line) and retentate (dashed line) on the degree of furfural extraction at permeate pressure of 1 and 10 kPa.

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10. Fig. 9. Dependence of the selection share on the degree of furfural extraction at a permeate pressure of 1 and 10 kPa.

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11. Fig. 10. Dependence of specific permeate productivity on the degree of furfural extraction at permeate pressure of 1 and 10 kPa.

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