Coupled electroreduction of CO2 and H+ in the presence of substituted salts of 2,2'-bipyridine

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The possibility of conjugate electroreduction of carbon dioxide and hydrogen in the presence of 2,2'-bipyridine and its N -substituted salts in the presence of acids with different pKa values was studied. It was revealed how the strength of the acid affects the efficiency of the process; in particular, it was determined that the presence of methylsulfonic acid in the system promotes the conjugate formation of hydrogen and the reduction of carbon dioxide to formic acid. Probable mechanisms for the reactions occurring have been proposed.

作者简介

E. Okina

National Research Ogarev Mordovia State University

L. Klimaeva

National Research Ogarev Mordovia State University

Email: l_klimaeva@mail.ru

D. Chugunov

National Research Ogarev Mordovia State University

S. Kostryukov

National Research Ogarev Mordovia State University

A. Kozlov

National Research Ogarev Mordovia State University

O. Tarasova

National Research Ogarev Mordovia State University

A. Yudina

National Research Ogarev Mordovia State University

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