Unusual Transformations of Allylsilanes in the Reactionwith N,N-Dichloroarenesulfonamides

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Аннотация

The reaction of dimethyl(chloromethyl)allylsilane and dimethyl- and diphenyl(diallyl)silanes with N , N -dichloroarenesulfonamides was studied. Due to the presence of active chlorine, in the reaction with monoallylsilane the products of chloroamination were obtained, whereas with diallylsilanes 4-chloro-1-sulfonyl-1,2-azasilolidines and 1-[(4-chlorophenyl)sulfonyl]-5,5-diphenyl-1,4,5,6-tetrahydro-1,5-azasilocine were formed in moderate yields.

Авторлар туралы

I. Ushakova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: lunav@irioch.irk.ru

B. Shainyan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

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