Highly dispersed Pd nanoparticles deposited on Sibunite by laser electrodispertion in Suzuki-Miyaura catalytic reaction

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Abstract

The paper presents the results of the study of the Suzuki-Miyaura reaction catalysis with aryl bromides using palladium catalyst precursors with a low metal content (10-2–10-1 wt %), deposited by laser electrodispersion of palladium on the surface of a carbon support (Sibunite). The analysis of the patterns of activity and stability of the synthesized catalysts, as well as their differential selectivity, along with an analysis of the changes in the state of the catalysts before the catalytic reaction and after its completion, allowed us to conclude that catalysis occurs with the participation of palladium nanoparticles and single atoms located on the surface of the carbon support.

About the authors

A. F. Schmidt

Irkutsk State University

Author for correspondence.
Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx Str.,1, Irkutsk, 664003

A. A. Kurokhtina

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx Str.,1, Irkutsk, 664003

E. V. Larina

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx Str.,1, Irkutsk, 664003

N. A. Lagoda

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx Str.,1, Irkutsk, 664003

T. A. Grigorieva

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx Str.,1, Irkutsk, 664003

I. N. Krotova

Lomonosov Moscow State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, Leninskie Gory 1 build 3., GSP-1, Moscow, 119991

K. I. Maslakov

Lomonosov Moscow State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, Leninskie Gory 1 build 3., GSP-1, Moscow, 119991

S. A. Nikolaev

Lomonosov Moscow State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, Leninskie Gory 1 build 3., GSP-1, Moscow, 119991

S. A. Gurevich

Ioffe Institute of the Russian Academy of Sciences

Email: aschmidt@chem.isu.ru
Russian Federation, Polytekhnicheskaya st., 26, St. Petersburg, 194021

D. A. Yavsin

Ioffe Institute of the Russian Academy of Sciences

Email: aschmidt@chem.isu.ru
Russian Federation, Polytekhnicheskaya st., 26, St. Petersburg, 194021

T. N. Rostovshchikova

Lomonosov Moscow State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, Leninskie Gory 1 build 3., GSP-1, Moscow, 119991

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