Современные промышленные и альтернативные методы получения алкиламинов

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Abstract

В обзоре проведен анализ современной научно-технической литературы, посвященной традиционным промышленным методам и новым альтернативным способам получения аминов, в частности, алкиламинов, с применением гетерогенных и гомогенных катализаторов. Рассмотрены основные направления превращения углеродсодержащих молекул при взаимодействии с аммиаком и другими азотсодержащими соединениями в амины различной степени замещенности. Выделены основные подходы к дизайну и получению катализаторов синтеза аминов. Освещены основные проблемы альтернативных способов их производства. Продемонстрирована возможность вовлечения в синтез алкиламинов техногенного диоксида углерода как одного из компонентов комплекса технологий улавливания, утилизации и хранения углерода (carbon capture, utilization and storage — CCUS).

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Оксана Сергеевна Дементьева

Институт нефтехимического синтеза им. А. В. Топчиева РАН

Author for correspondence.
Email: dementyeva@ips.ac.ru
ORCID iD: 0000-0001-6801-0158

с. н. с., к. х. н.

Russian Federation, Москва, 119991

Антон Витальевич Борисов

Институт нефтехимического синтеза им. А. В. Топчиева РАН; Российский государственный университет нефти и газа (НИУ) имени И. М. Губкина

Email: dementyeva@ips.ac.ru
ORCID iD: 0009-0009-5217-5527

ст. лаборант

Russian Federation, Москва, 119991; Москва, 119991

Степан Дмитриевич Баженов

Институт нефтехимического синтеза им. А. В. Топчиева РАН

Email: dementyeva@ips.ac.ru
ORCID iD: 0000-0002-2010-5294

зав. лаб., к. х. н.

Russian Federation, Москва, 119991

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Supplementary files

Supplementary Files
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1. JATS XML
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2. Fig. 1. Amine demand in 2022 and projected consumption as of 2032 (adapted from [4]).

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3. Fig. 2. Raw materials, intermediates and catalysts of the process of amine production from alcohols (adapted from [67]).

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4. Fig. 3. Co-reduction of carbon oxides and nitrogen-containing compounds to form amines (adapted from [51]).

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5. Fig. 4. Examples of C-N bond formation pathways in heterogeneous catalysis (adapted from [51]).

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6. Fig. 5. Examples of C-N bond formation pathways in enzymatic catalysis (adapted from [51]).

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7. Fig. 6. Examples of ω-transaminase oxidoreductase cascades (A) and (B): synthesis of primary chiral amines from the corresponding secondary alcohols (adapted from [94]).

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8. Fig. 7. Example of the C-N bond formation pathway in molecular catalysis by Buchwald-Hartwig cross-coupling (adapted from [51]).

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9. Fig. 8. Reaction for the preparation of amines according to Ritter.

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10. Fig. 9. Reaction of isobutylene with ammonia on solid acid catalysts.

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11. Fig. 10. Total regioselective reaction of amine addition to olefin (adapted from [57]).

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12. Fig. 11. Mechanism of amine formation in the modified Fischer-Tropsch synthesis (adapted from [62]).

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13. Fig. 12. Schematic of production of high value-added products by catalytic binding of carbon dioxide and ammonia.

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14. Fig. 13. Possible pathways for the ruthenium-catalysed ammonia methylation reaction using CO2 as a source of the C1 fragment (adapted from [162]).

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