GROWTH, STRUCTURE, AND PHASE BEHAVIOR OF DI-TERT-BUTYL-PARA-TERPHENYL CRYSTALS

V. A. Postnikov; Постников В. А.; N. I. Sorokina; Сорокина Н. И.; A. A. Kulishov; Кулишов А. А.; G. A. Yurasik; Юрасик Г. А.; M. S. Lyasnikova; Лясникова М. С.; T. A. Sorokin; Сорокин Т. А.; M. S. Skorotetsky; Скоротецкий М. С.; O. V. Borshchev; Борщев О. В.

doi:10.31857/S0023476123010228

GROWTH, STRUCTURE, AND PHASE BEHAVIOR OF DI-TERT-BUTYL-PARA-TERPHENYL CRYSTALS

作者: Postnikov V.A.¹, Sorokina N.I.¹, Kulishov A.A.¹, Yurasik G.A.¹^,2, Lyasnikova M.S.¹, Sorokin T.A.¹, Skorotetsky M.S.³, Borshchev O.V.³
隶属关系:
1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia
2. Center of Photochemistry, Federal Scientific Research Centre“Crystallography and Photonics,”Russian Academy of Sciences, Moscow, Russia
3. Enikopolov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, Russia
期: 卷 68, 编号 1 (2023)
页面: 121-130
栏目: CRYSTAL GROWTH
URL: https://ter-arkhiv.ru/0023-4761/article/view/673567
DOI: https://doi.org/10.31857/S0023476123010228
EDN: https://elibrary.ru/DQQVUI
ID: 673567

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
作者简介
参考
补充文件
统计

详细

The results of studying the growth of para-terphenyl derivative (4,4"-di-tert-butyl-para-terphenyl (tBu-3P-tBu)) crystals are presented. The solubility of this compound in toluene at 20°С has been established by spectrophotometry. Using the techniques of growth from solutions and physical vapor transport,tBu-3P-tBu single crystals up to 1 cm long have been obtained for the first time. Their structure at 85 K has been interpreted in the triclinic system, sp. gr. P1 (Z = 8), using single-crystal X-ray diffraction. Flat rectangular crystals with the best morphological characteristics have been grown from vapor. The developed face of these crystals exhibits elementary growth steps 1.4 nm high, corresponding to molecular monolayers oriented in the (001) plane. The presence of a polymorphic transition at 229.2°C and mesomorphic liquid crystal phase above the melting temperature (255.6°С) is found.

关键词

GROWTH, STRUCTURE, PHASE BEHAVIOR, DI-TERT-BUTYL-PARA-TERPHENYL CRYSTALS

作者简介

V. Postnikov

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia

Email: postva@yandex.ru
Россия, Москва

N. Sorokina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia

Email: postva@yandex.ru
Россия, Москва

A. Kulishov

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia

Email: postva@yandex.ru
Россия, Москва

G. Yurasik

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia; Center of Photochemistry, Federal Scientific Research Centre“Crystallography and Photonics,”Russian Academy of Sciences, Moscow, Russia

Email: postva@yandex.ru
Россия, Москва; Россия, Москва

参考

Birks J.B. The Theory and Practice of Scintillation Counting: International Series of Monographs on Electronics and Instrumentation. Pergamon Press Ltd, 1967. 662 p. https://doi.org/10.1016/C2013-0-01791-4
Красовицкий Б.М., Болотин Б.М. Органические люминофоры. 2-е изд. М.: Химия, 1984. 336 с.
Matei C., Hambsch F.J., Oberstedt S. // Nucl. Instrum. Methods Phys. Res. A. 2012. V. 676. P. 135. https://doi.org/10.1016/j.nima.2011.11.076
Liao H.R., Lin Y.J., Chou Y.M. et al. // J. Lumin. 2008. V. 128. P. 1373. https://doi.org/10.1016/j.jlumin.2008.01.006
Gershuni S., Rabinovitz M., Agranat I. et al. // J. Phys. Chem. 1980. V. 84. P. 517. https://doi.org/10.1021/j100442a013
Yemam H.A., Mahl A., Tinkham J.S. et al. // Chem. Eur. J. 2017. V. 23. P. 8921. https://doi.org/10.1002/chem.201700877
Постников В.А., Сорокина Н.И., Алексеева О.А. и др. // Кристаллография. 2018. Т. 63. С. 801. https://doi.org/10.1134/s0023476118050247
Pålsson L.O., Nehls B.S., Galbrecht F. et al. // J. Phys. Chem. B. 2010. V. 114. P. 12765. https://doi.org/10.1021/jp1028883
Корешков А.П. Основы аналитической химии. Т. 3. М.: Химия, 1970. 472 с.
Постников В.А., Кулишов А.А., Лясникова М.С. и др. // Кристаллография. 2021. Т. 66. С. 494. https://doi.org/10.31857/s0023476121030206
Postnikov V.A., Sorokina N.I., Lyasnikova M.S. et al. // Crystals. 2020. V. 10. P. 363. https://doi.org/10.3390/cryst10050363
Nagahara L.A. // J. Vac. Sci. Technol. B. 1994. V. 12. P. 1694. https://doi.org/10.1116/1.587265
Nečas D., Klapetek P. Gwiddion Software: 2.59.
Rigaku Oxford Diffraction: 1.171.39.46. Rigaku Corporation, Oxford, UK, 2018.
Petrícek V., Dušek M., Palatinus L. // Z. Kristallogr. 2014. B. 229. S. 345. https://doi.org/10.1515/zkri-2014-1737
Palatinus L. // Acta Cryst. A. 2004. V. 60. P 604. https://doi.org/10.1107/S0108767304022433
Ried W., Freitag D. // Angew. Chem. 1968. V. 80. P. 932. https://doi.org/10.1002/ange.19680802203
Ландсберг Г.С. Оптика. 7-е изд. М.: ФИЗМАТЛИТ, 2017. 852 с.
Postnikov V.A., Odarchenko Y.I., Iovlev A. V. et al. // Cryst. Growth Des. 2014. V. 14. P. 1726. https://doi.org/10.1021/cg401876a
MercurySoftware: 2021.1.0. CCDC.