Enviar artigo por via de e-mail SYNTHESIS AND STRUCTURE OF NEW [5]FERROCENOPHANE
- Autores: Medved’ko A.V.1, Churakov A.V.2, Krut’ko D.P.3, Vatsadze S.Z.1
-
Afiliações:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Department of Chemistry, Lomonosov Moscow State University
- Edição: Volume 513, Nº 1 (2023)
- Páginas: 62-66
- Seção: CHEMISTRY
- URL: https://ter-arkhiv.ru/2686-9535/article/view/651932
- DOI: https://doi.org/10.31857/S2686953523600095
- EDN: https://elibrary.ru/CCEEDQ
- ID: 651932
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
The first example of intramolecular diastereoselective domino reaction of ferrocene 1,1'-bis-enone to [5]ferrocenophane initiated with sodium ethylate was found. The product is [5]ferrocenophane with two pyridyl and one ethoxy substituents arranged asymmetrically in five carbon bridge. Diffraction studies showed that ferrocene is in almost ideal eclipsed conformation. The fan conformation found in the crystal is also preserved in solution, which was determined by NMR spectroscopy.
Palavras-chave
Sobre autores
A. Medved’ko
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: zurabych@gmail.com
Russian Federation, 119991
A. Churakov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zurabych@gmail.com
Russian Federation, 119991
D. Krut’ko
Department of Chemistry, Lomonosov Moscow State University
Email: zurabych@gmail.com
Russian Federation, 119991
S. Vatsadze
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: zurabych@gmail.com
Russian Federation, 119991
Bibliografia
- Wirtz L., Schäfer A. // Chem. – Eur. J. 2021. V. 27. № 4. P. 1219–1230. https://doi.org/10.1002/chem.202003161
- Heo R.W., Lee T.R. // J. Organom. Chem. 1999. V. 578. № 1–2. P. 31–42. https://doi.org/10.1016/S0022-328X(98)01126-7
- Moriuchi T., Hirao T., Ikeda I. // Organometallics. 1995. V. 14. № 7. P. 3578–3580. https://doi.org/10.1021/om00007a069
- Foucher D.A., Tang B.Z., Manners I. // J. Am. Chem. Soc. 1992. V. 114. № 15. P. 6246–6248. https://doi.org/10.1021/ja00041a053
- Tárraga A., Molina P., Luis López J. // Tetrahedron Lett. 2000. V. 41. № 14. P. 2479–2482. https://doi.org/10.1016/S0040-4039(00)00184-2
- Pedotti S., Patti A. // J. Organomet. Chem. 2008. V. 693. № 7. P. 1375–1381. https://doi.org/10.1016/j.jorganchem.2008.01.038
- Liu W.W., Xu Q., Chen B., Liang Y., Ma Y., Liu W.W. // J. Organomet. Chem. 2001. V. 637–639. № 2–3. P. 782–785. https://doi.org/10.1016/S0022-328X(01)00927-5
- Barr T.H., Watts W.E. // Tetrahedron. 1968. V. 24. № 8. P. 3219–3235. https://doi.org/10.1016/S0040-4020(01)92620-1
- Constable E.C., Edwards A.J., Marcos M.D., Raithby P.R., Martinez-Manez R., Tendero M.J. // Inorg. Chim. Acta. 1994. V. 224. № 1–2. P. 11–14. https://doi.org/10.1016/0020-1693(94)04147-4
- Zakaria C.M., Ferguson G., Lough A.J., Glidewell C. // Acta Crystallogr., Sect. B: Struct. Sci. 2002. V. 58. № 5. P. 786–802. https://doi.org/10.1107/S010876810200976X
- Medved’ko A.V., Churakov A.V., Yu H., Li W., Vatsa-dze S.Z. // Acta Cryst., Sect. E: Cryst. Commun. 2017. V. 73. № 6. P. 856–858. https://doi.org/10.1107/S2056989017007058
- Sheldrick G.M. SADABS, Program for Scanning and Correction of Area Detector Data. Götinngen, Germany: Götinngen University, 2004.
- Sheldrick G.M. // Acta Crystallogr., Sect. A: Found. Crystallogr. 2008. V. 64. № Pt 1. P. 112–122. https://doi.org/10.1107/S0108767307043930
Arquivos suplementares
