DIPINODIAZAFLUORENES AS REAGENTS FOR SELECTIVE EXTRACTION OF PALLADIUM, GOLD AND RUTHENIUM

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Abstract

Dipinodiazafluorenes are hybrid nopinane-annelated heterocycles whose molecules include a heterocyclic core of 4,5-diazafluorene condensed with fragments of terpene hydrocarbon, capable of selectively extracting palladium (88−100%), gold (42−96%) and ruthenium (8−19%) by single extraction from acidic aqueous solutions (pH 1.2) containing complex mixtures of 3d-elements and precious metals.

About the authors

D. V. Zubricheva

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences

Email: atkachev@nioch.nsc.ru
Russian, 630090, Novosibirsk

E. S. Vasilyev

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences

Email: atkachev@nioch.nsc.ru
Russian, 630090, Novosibirsk

S. N. Bizyaev

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences

Email: atkachev@nioch.nsc.ru
Russian, 630090, Novosibirsk

V. D. Tikhova

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences

Email: atkachev@nioch.nsc.ru
Russian, 630090, Novosibirsk

A. V. Tkachev

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: atkachev@nioch.nsc.ru
Russian, 630090, Novosibirsk

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Copyright (c) 2023 Д.В. Зубричева, Е.С. Васильев, С.Н. Бизяев, В.Д. Тихова, А.В. Ткачев