Email this article 
NEW CONCEPTS OF COLLOID SCIENCE: NANO-ADSORBENT AND PROTOMICELLE
- Authors: Rusanov A.I.1,2, Movchan T.G.1, Plotnikova E.V.1
-
Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
- St. Petersburg State University
- Issue: Vol 512, No 1 (2023)
- Pages: 114-119
- Section: PHYSICAL CHEMISTRY
- URL: https://ter-arkhiv.ru/2686-9535/article/view/651960
- DOI: https://doi.org/10.31857/S2686953523700218
- EDN: https://elibrary.ru/JWVTOC
- ID: 651960
Cite item
Open Access
Access granted
Subscription Access
Abstract
Large molecules of dyes or other substances can play the role of a nano-adsorbent in aqueous surfactant solutions and, coated with surfactant molecules, resemble surfactant micelles with a solubilizate. Such micelle-like particles were called protomicelles. Their formation does not require a critical micelle concentration (CMC) and begins immediately when the surfactant is introduced into the solution. In this spectrophotometric study of Nile red (NR) in aqueous solutions of nonanoic acid (NOA), the case where protomicelles are more important than micelles is demonstrated for the first time. It has been shown that the solubilization of NR in both premicellar and micellar solutions proceeds through protomicelles rather than NOA micelles. The article also contains a theoretical part. In it, on the basis of the chemical potential of the nano-adsorbent, it is proved that the addition of a surfactant to a solution always increases the solubility of the nano-adsorbent. The dependence of adsorption on the curvature of the nano-adsorbent surface is considered and it is shown that the adsorption equations for flat surfaces can be used for curved surfaces with high accuracy.
About the authors
A. I. Rusanov
Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences; St. Petersburg State University
Author for correspondence.
Email: airusanov@mail.ru
Russian Federation, 119071, Moscow; Russian Federation, 199034, St. Petersburg
T. G. Movchan
Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: airusanov@mail.ru
Russian Federation, 119071, Moscow
E. V. Plotnikova
Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: airusanov@mail.ru
Russian Federation, 119071, Moscow
References
- Русанов А.И., Мовчан Т.Г., Плотникова Е.В. // Докл. РАН. Химия, науки о материалах. 2020. Т. 495. С. 60–65. https://doi.org/10.31857/S2686953520060126
- Rusanov A.I. // Colloids Surf., A. 2021. V. 629. P. 127453. https://doi.org/10.1016/j.colsurfa.2021.127453
- Куни Ф.М., Русанов А.И. // Теор. Мат. Физ. 1970. Т. 2. С. 265–285.
- Zhu P.W., Napper D.H. // Colloids Surf., A. 1996. V. 113. P. 145–153. https://doi.org/10.1016/0927-7757(96)03520-0
- El-Ejmi A.A.S., Huglin M.B. // Eur. Polym. J. 1997. V. 33. P. 1281–1284. https://doi.org/10.1016/S0014-3057(96)00272-8
- Мовчан Т.Г., Русанов А.И., Плотникова Е.В. // Коллоид. журн. 2021. Т. 83. С. 335–343. https://doi.org/10.31857/S0023291221030125
- Мовчан Т.Г., Русанов А.И., Плотникова Е.В. // Коллоид. журн. 2021. Т. 83. С. 443–448. https://doi.org/10.31857/S0023291221040066
- Movchan T.G., Rusanov A.I., Plotnikova E.V. // Russ J. Org. Chem. 22. V. 92. № 10. P. 2023–2032. https://doi.org/10.1134/S1070363222100164
- Rusanov A.I., Movchan T.G., Plotnikova E.V. // Molecules. 2022. V. 27. P. 7667. https://doi.org/10.3390/molecules27227667
- Badban S., Hyde A.S., Phan C.M. // ACS Omega. 2017. V. 2. P. 5565–5573. https://doi.org/10.1021/acsomega.7b00960
- Tanford Ch. The hydrophobic effect. Micelles and biological membranes. New York: Wiley, 1973.
- Русанов А.И. Мицеллообразование в растворах поверхностно-активных веществ. СПб.: Химия, 1992.
- Rusanov A.I. Micellization in surfactant solutions. Harwood Academic Publishers: Reading, UK, 1996. 326 p. ISBN 90-5702-297-4.
- Русанов А.И., Щёкин А.К. Мицеллообразование в растворах поверхностно-активных веществ, 2-е изд., доп. СПб.: Лань, 2016. 612 с.
- Yalkowsky S.H., He Y., Jain P. Handbook of Aqueous Solubility Data. 2nd Ed. London: CRC Press, 2010. 1620 p.
- Селиванов Н.И., Самсонова Л.Г., Артюхов В.Я., Копылова Т.Н. // Изв. вузов. Физика. 2011. Т. 54. № 5. С. 85–90. https://doi.org/10.1007/s11182-011-9658-4
- Русанов А.И. // Коллоид. журн. 2021. Т. 83. С. 98–106.https://doi.org/10.31857/S0023291220060117
- Kurniasih I.N., Liang H.P., Mohr P.Ch., Khot G., Rabe J.P., Mohr A. // Langmuir. 2015. V. 31. P. 2639–2648. https://doi.org/10.1021/la504378m
Supplementary files
