Composite Solid Electrolytes

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Abstract

The review describes composite electrolytes based on classical salt matrix phases, and also shows the possibilities of creating composites using simple or complex oxide matrices, where simple substances, salts, simple and complex oxides are used as heterogeneous dopant. The magnitude of the composite effect of electrical conductivity is discussed from the point of view of various theories of its quantitative description. The reasons for the occurrence of the composite effect are summarized. The effect of increasing ionic conductivity is due to the disorder of the surface layer in the intergranular space, amorphization or spreading of the matrix phase or the phase of heterogeneous dopant over the surface of the other phase due to the difference in surface energy, as well as the possibility of joint manifestation of these effects when using complex oxide eutectic composites with treatment above the temperature of the eutectic system.

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E. S. Matveev

Ural Federal University named after the first President of Russia B.N. Yeltsin

Author for correspondence.
Email: Egor.Matveev@urfu.ru
Russian Federation, Ekaterinburg

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2. Fig. 1. Concentration dependence of relative electrical conductivity of samples in the system (1–x)A·xSND (A = AgI, LiClO4) [22-24]. The graph was made by the author of the review based on the data of publications [22–24]

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3. Fig. 2. Concentration dependences of relative electrical conductivity of composites in systems based on CsH2PO4 [27] and LiTi2(PO4)3/LiClO4 [31] salts. The graph is made by the author of the review based on the data of publications [27, 31]

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4. Fig. 3. Concentration dependences of relative electrical conductivity of samples in composite systems based on MLn2S4 (M = Ba, Ca; Ln = Y, Sm, Yb) [32–34]. The graph was made by the author of the review based on the data of publications [32–34]

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5. Fig. 4. Concentration dependences of relative electrical conductivity for samples in the systems CsH2PO4 – SrZrO3 [46], CsNO2 – MgAl2O4 [47] and LiClO4 – MgAl2O4 [48]. The graph was made by the author of the review based on the data of the publication [46–48]

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6. Fig. 5. Concentration dependences of the total electrical conductivity of samples in the Ba2In2O5–Ba2InTaO6 system [53] obtained in air atmosphere with different humidity. The graph was made by the author of the review based on the data of the publication [53]

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7. Fig. 6. Concentration dependence of the relative bulk electrical conductivity of samples in the La2Mo2O9–La2Mo3O12 system [56]. The graph was made by the author of the review based on the data of the publication [56]

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8. Fig. 7. Scheme of microstructural features of composites in systems with spreading of salt phase on another phase

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9. Fig. 8. Scheme of microstructural features of composites in systems with the formation of a new highly conductive phase different in composition from the initial phases

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10. Fig. 9. Scheme of microstructural features of composites in systems with the formation of crystalline disordered phases during crystallisation of eutectics with submicron-sized grains

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