Ring Silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 As Merohedral Twins

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Resumo

New ring silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 have been synthesized by the hydrothermal method. A structural analogy is revealed between them and the previously studied silicates K4Sc2(OH)2(Si4O12) and K2Sc[Si2O6]F. Their crystal structures are identified as orthorhombic merohedral twins by the lost element of tetragonal symmetry. The structures of new ring silicates are related to those of fresnoite and tetragonal melilite.

Sobre autores

N. Bolotina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

A. Topnikova

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

E. Belokoneva

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

O. Dimitrova

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

A. Volkov

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

L. Zorina

Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

Autor responsável pela correspondência
Email: bolotina@crys.ras.ru
Россия, Черноголовка

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